from this site:
http://www.porcelainenamel.com/pei502.htm
enamal COE's range from 80 to 140 depending on composition. Enamel is stronger in compression, so if there is a COE mismatch, it's better if the enamel has a lower COE than the metal. Maybe that's why some people have had success with 104 COE enamel on 170 COE copper?